Search results for "Co release"

showing 2 items of 2 documents

Manganese carbonyl terpyridyl complexes: their synthesis, characterization and potential application as CO-release molecules

2014

MnI carbonyl terpyridyl complexes have been synthesized and characterized. The tricarbonyl derivative exhibits interesting behaviors for controlled CO-release by both thermal and photosynthetic pathways.

Carbon MonoxideManganeseLightMetals and Alloyschemistry.chemical_elementGeneral ChemistryManganesePhotosynthesisPhotochemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCharacterization (materials science)chemistry.chemical_compoundchemistryCoordination ComplexesMaterials ChemistryCeramics and CompositesMolecule[CHIM]Chemical SciencesCo releaseta116Derivative (chemistry)ComputingMilieux_MISCELLANEOUSChemical Communications
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Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation.

2020

The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.

Inorganic ChemistryCo deliveryChemistryIrradiationPhysical and Theoretical ChemistryCo releaseLuminescencePhotochemistryBlue lightInorganic chemistry
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